Roden, J.S., and J.R. Ehleringer. 2000. Hydrogen and oxygen isotope ratios of tree-ring cellulose for field grown riparian trees. Oecologia 123:481-489.
Abstract The isotopic composition of tree ring cellulose was
obtained over a 2-year period from small-di-ameter
riparian-zone trees at field sites that differed in source water
isotopic composition and humidity. The sites were located in Utah
(cool and low humidity), Oregon (cool and high humidity), and
Arizona (warm and low humidity) with source water isotope ratio
values of 125/15 (dD/d 18 O), 48/6, and 67/7,
respectively. Monthly environmental measurements included temperature
and humidity along with measurements of the isotope ratios in
atmospheric water vapor, stream, stem, and leaf water. Small riparian
trees used only stream water (both dD and d 18 O of stem and stream
water did not differ), but d values of both atmospheric water
vapor and leaf water varied substantially between months. Differences
in ambient temperature and humidity conditions between sites contributed
to substantial differences in leaf water evaporative enrichment.
These leaf water differences resulted in differences in the dD
and d 18 O values of tree ring cellulose, indicating that humidity
information was recorded in the annual rings of trees. These environmental
and isotopic measurements were used to test a mechanistic model
of the factors contributing to dD and d 18 O values in tree ring
cellulose. The model was tested in two parts: (a) a leaf water
model using environmental information to predict leaf water evaporative
enrichment and (b) a model describing bio-chemical fractionation
events and isotopic exchange with medium water. The models adequately
accounted for field observations of both leaf water and tree ring
cellulose, indicating that the model parameterization from controlled
experiments was robust even under uncontrolled and variable field
conditions.